SOLUBILITY OF GASES IN LIQUIDS .19. SOLUBILITY OF HE, NE, AR, KR, XE,N2, O2, CH4, CF4, AND SF6 IN NORMAL 1-ALKANOLS -LESS-THAN-OR-EQUAL-TO-L-LESS-THAN-OR-EQUAL-TO-11) AT 298.15-K(1OH (1)
Sq. Bo et al., SOLUBILITY OF GASES IN LIQUIDS .19. SOLUBILITY OF HE, NE, AR, KR, XE,N2, O2, CH4, CF4, AND SF6 IN NORMAL 1-ALKANOLS -LESS-THAN-OR-EQUAL-TO-L-LESS-THAN-OR-EQUAL-TO-11) AT 298.15-K(1OH (1), Journal of chemical and engineering data, 38(4), 1993, pp. 611-616
The Ostwald coefficients L2,1 of He, Ne, Ar, Kr, Xe, N2, O2, CH4, CF4,
and SF6 dissolved in several homologous alkan-1-ols, n-ClH2l+1OH,1 le
ss-than-or-equal-to l less-than-or-equal-to 11, have been determined a
t 298.15 K and atmospheric pressure. Altogether, 102 gas/liquid system
s were investigated. The medium precision apparatus (about +/-0.5%) wa
s of the Ben-Naim/Baer type, similar to our recently published design.
Data reduction is presented in some detail, including the estimation
of auxiliary quantities, such as second virial coefficients and partia
l molar volumes at infinite dilution. The effect of chain length l is
shown, and several correlations between L2,1 (and/or the derived Henry
fugacity H-2, H-1) and appropriate molecular and/or bulk properties o
f the gases and solvents are discussed.