Al(111) oxidation has been subjected to numerous studies using surface
analysis techniques. Indeed it seems to have been used as a proving g
round for techniques to establish the detail each can shed on the dete
rmination of the adsorption site of O on a clean Al(111) surface. In t
his first detailed ion scattering study of the oxidation of the Al(111
) surface it has been established that at exposures of up to 100 L alm
ost one monolayer of oxygen is adsorbed to the surface. This observati
on alone brings into question many models which conclude that the adso
rption leads to a surface, and subsurface layer of oxygen. Furthermore
, by using shadowing and blocking associated with medium energy ion sc
attering (MEIS) it has been possible to exclude the existence of a sig
nificant subsurface site at exposures up to 100 L.