Steam explosion pulps were studied by means of CP/MAS C-13 NMR spectro
scopy. The steam explosion treatment of aspen chips with Na2SO3 and Na
2SO3 + NaOH led to a loss in hemicellulose and an increase in cellulos
e crystallinity. No lignin dissolution occurred during explosion pulpi
ng, although the lignin structure might have changed to a certain exte
nt. For comparison purposes, conventional CMP and CTMP pulps were also
analyzed. The conventional treatments revealed less modification in t
he spectrum with regard to original wood samples.