M. Condomines et O. Sigmarsson, WHY ARE SO MANY ARC MAGMAS CLOSE TO U-238 TH-230 RADIOACTIVE EQUILIBRIUM, Geochimica et cosmochimica acta, 57(18), 1993, pp. 4491-4497
New analyses of U-238-Th-230 disequilibria are reported for four activ
e volcanoes: Merapi and Krakatoa in the Sunda arc (Indonesia), Masaya
in Central America (Nicaragua), and Ambrym in the New Hebrides island
arc. Despite a large range in (Th-230/Th-232) ratios (from 0.65 in Mer
api andesites to 2.5 in Masaya basalts), U-238 and Th-230 are close to
radioactive equilibrium, as in many other arc magmas. In several mant
le sources, Th/U ratios have clearly been modified by metasomatic proc
esses associated with subduction. This is demonstrated in Central Amer
ica by the correlation between (Th-230/Th-232) and Be-10/Be-9 ratios f
or several active volcanoes along the arc. It is proposed that the U-2
38-Th-230 radioactive equilibrium found in many arc magmas is the resu
lt of disequilibrium melting involving an easily melted, slab-derived,
metasomatic component which dominates the uranium and thorium budget
of the mantle sources. The departure from equilibrium may be either du
e to mixing with Th-230 enriched melts derived from unmetasomatized ma
ntle sources or to a late stage uranium addition by fluids. This latte
r process, producing uranium enriched magmas, has a greater influence
in uranium and thorium poor magmas.