H. Rouch et al., MODELING OF CVD REACTORS - THERMOCHEMICAL AND MASS-TRANSPORT APPROACHES FOR SI1-XGEX DEPOSITION, Journal de physique. IV, 3(C3), 1993, pp. 17-23
Over the years, the design of chemical vapor deposition processes has
relied on accumulated empirical ability. It is now well established th
at the properties of films grown by this chemical process are strongly
determined by both transport phenomena and homogeneous and heterogene
ous reactions in the reactor. Thermodynamic calculations and mass tran
sport modeling provide a possible approach to delineate the general fe
atures of a given process. The application of this concept to the depo
sition of Si1-xGex alloys has led to a better knowledge of the physico
chemical phenomena involved in the growth of these materials.