The deposition process of IV-VI semiconductors is studied in order to
determine optimal conditions of evaporation. A thermodynamical model o
f the growth is proposed and its use explained in HWE applications. Us
ing these results, epitaxial thin films have been achieved on BaF2 and
Si substrates in all the composition range from PbSe to PbTe. The epi
layers obtained were then characterized by X-ray diffraction, Auger sp
ectroscopy, SEM observations and electrical measurements. An optical s
tudy from 4.2 to 300K is finally presented and the energy band gap dep
endence versus composition and temperature has been established.