J. Murota et al., SI SI1-X GEX/SI HETEROSTRUCTURE GROWTH BY ULTRACLEAN LOW-TEMPERATURE LPCVD FOR THE FABRICATION OF NOVEL HETERODEVICE/, Journal de physique. IV, 3(C3), 1993, pp. 403-410
Low-temperature epitaxial growth of Si/Si1-xGex/Si heterostructures at
high Ge fractions on Si(100) was investigated under the cleanest poss
ible reaction environment of SiH4, GeH4 and H-2 or Ar using an ultracl
ean hot-wall low-pressure chemical vapour deposition (LPCVD) system. I
t was found that relatively lower deposition temperatures were suitabl
e for higher Ge fractions in order to prevent island growth of the lay
ers during deposition. Atomically flat surfaces and interfaces for the
heterostructure containing Si0.8Ge0.2, Si0.5Ge0.5 and Si0.3Ge0.7 laye
rs were obtained by deposition at 550, 500 and 450-degrees-C, respecti
vely. Cross-sectional transmission electron microscope (TEM) images an
d Raman spectra show that such samples have excellent epitaxial qualit
ies which are not degraded by wet oxidation for 2 hours at 700-degrees
-C. The Si0.5Ge0.5-channel metal-oxide-semiconductor field-effect tran
sistor (MOSFET) having a flat surface has the highest peak field-effec
t mobility, resulting in the large mobility enhancements of about 70%
at 300K and over 150% at 77K compared with those of the MOSFET without
the Si1-xGex-channel.