RABEJACITE, CA(UO2)4(SO4)2(OH)6-CENTER-DO T-6H2O, NEW URANYL AND CALCIUM-SULFATE FROM LODEVE, HERAULT, FRANCE

Authors
Citation
M. Deliens et P. Piret, RABEJACITE, CA(UO2)4(SO4)2(OH)6-CENTER-DO T-6H2O, NEW URANYL AND CALCIUM-SULFATE FROM LODEVE, HERAULT, FRANCE, European journal of mineralogy, 5(5), 1993, pp. 873-877
Citations number
10
Categorie Soggetti
Mineralogy
ISSN journal
09351221
Volume
5
Issue
5
Year of publication
1993
Pages
873 - 877
Database
ISI
SICI code
0935-1221(1993)5:5<873:RCTNUA>2.0.ZU;2-N
Abstract
Rabejacite occurs as flattened tablets (up to 0.1 mm), acicular crysta ls or rounded nodules (up to 0.3 mm). Bright to amber yellow and trans parent to translucent with a vitreous luster. Light yellow fluorescenc e under short-wave and long-wave UV lights. Optically 2V (-) with alph a(calc) = 1.617, beta = 1.710, gamma = 1.758, 2V (meas.) = 68-degrees. Optical orientation, X = c, Y and Z in the plane of the tablets. Syst em orthorhombic, a = 8.73(1), b = 17.09(2), c = 15.72(2) angstrom, Z = 4, D(calc.) = 4.31 g/cm3, D(meas) greater-than-or-equal-to 4.10 g/cm3 . The strongest lines in the X-ray powder pattern are (d(angstrom),I,h kl) 7.90 (100) 002, 3.49 (80) 222 & 230, 3.38 (70) 231, 3.98 (40) 123, 4.17 (30) 201. The average of 20 electron-microprobe analyses gave: C aO 2.78%, UO3 76.62%, SO3 10.43%, H2O (by chromatography) 10.18%. Empi rical formula Ca0.76 (UO2)4.15(SO4)2.02(OH)5.78 . 5.86 H2O or ideally Ca(UO2)4(SO4)2(OH)6. 6H2O. Rabejacite was found in two deposits of the Permian basin of Lodeve: in the red Saxonian pelites from Rabejac (7 km S-SE from Lodeve) and in the gray Autunian from Mas d'Alary Village (3 km S-SE from Lodeve). The mineral appears in the alteration zone a nd forms mixed crusts together with gypsum. The name is for the locali ty of the first discovery.