ANALYTICAL PERFORMANCES OF LIPOPHILIC DIAMIDES BASED ALKALINE-EARTH ION-SELECTIVE ELECTRODES

Authors
TOTH K LINDNER E HORVATH M JENEY J PUNGOR E BITTER I AGAI B TOKE L
Citation
K. Toth et al., ANALYTICAL PERFORMANCES OF LIPOPHILIC DIAMIDES BASED ALKALINE-EARTH ION-SELECTIVE ELECTRODES, Electroanalysis, 5(9-10), 1993, pp. 781-790
Citations number
25
Categorie Soggetti
Chemistry Analytical
Journal title
Electroanalysis → ACNP
ISSN journal
10400397
Volume
5
Issue
9-10
Year of publication
1993
Pages
781 - 790
Database
ISI
SICI code
1040-0397(1993)5:9-10<781:APOLDB>2.0.ZU;2-E
Abstract
Based on complex chemical considerations, lipophilic diamide derivativ es have been designed and synthesized as ionophores for liquid membran e electrodes. The structure-selectivity studies revealed that the majo rity of the ligands exhibit calcium ion selectivity except the compoun d bis-N,N-dicyclohexyl-malonamide. The latter has an almost equal sele ctivity for Ca2+ and Mg2+ and sufficiently rejects sodium ions, thus i t lends itself to water hardness measurements.