FLUORIDE-ION IN GROUP-6 METAL-CARBONYL CHEMISTRY - AN UNEXPECTED PROMOTER OF CARBONYLATIVE INSERTIONS IN ORGANIC AND ORGANOMETALLIC ENYNES

Authors
JORDI L SEGUNDO A CAMPS F RICART S MORETO JM
Citation
L. Jordi et al., FLUORIDE-ION IN GROUP-6 METAL-CARBONYL CHEMISTRY - AN UNEXPECTED PROMOTER OF CARBONYLATIVE INSERTIONS IN ORGANIC AND ORGANOMETALLIC ENYNES, Organometallics, 12(10), 1993, pp. 3795-3797
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
10
Year of publication
1993
Pages
3795 - 3797
Database
ISI
SICI code
0276-7333(1993)12:10<3795:FIGMC->2.0.ZU;2-W
Abstract
Ready carbonylative cycloadditions were observed in the protodesilylat ion of trimethylsilyl)alkynyl)(diallylamino)carbene)metal complexes me diated by fluoride ions. A study of the ability of this ion to activat e the ''(CO)5M'' fragments for an efficient carbonylative insertion pr ocess was carried out and extended to organic enynes.