2 WAYS TO TRANSFER A PROTON - AN AB-INITIO STUDY OF THE IDENTITY REACTION OF SIH3-+SIH4 AND COMPARISONS TO THE REACTIONS OF ALH3 AND PH3

Authors
GRONERT S
Citation
S. Gronert, 2 WAYS TO TRANSFER A PROTON - AN AB-INITIO STUDY OF THE IDENTITY REACTION OF SIH3-+SIH4 AND COMPARISONS TO THE REACTIONS OF ALH3 AND PH3, Organometallics, 12(10), 1993, pp. 3805-3807
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
10
Year of publication
1993
Pages
3805 - 3807
Database
ISI
SICI code
0276-7333(1993)12:10<3805:2WTTAP>2.0.ZU;2-U
Abstract
High-level ab initio calculations (G2+) indicate that, in the reaction of SiH3- + SiH4, there are two, competitive mechanisms for proton tra nsfer. Comparisons to the analogous reactions of PH3 and AlH3 are made .