THE LAPLACE TRANSFORM OF THE MSA PAIR DISTRIBUTION-FUNCTIONS BETWEEN MACROIONS IN AN ION DIPOLE FLUID

Authors
HOLOVKO MF TROKHYMCHUK AD PROTSYKEVICH IA HENDERSON DJ
Citation
Mf. Holovko et al., THE LAPLACE TRANSFORM OF THE MSA PAIR DISTRIBUTION-FUNCTIONS BETWEEN MACROIONS IN AN ION DIPOLE FLUID, Journal of statistical physics, 72(5-6), 1993, pp. 1391-1399
Citations number
21
Categorie Soggetti
Mathematical Method, Physical Science","Physycs, Mathematical
Journal title
Journal of statistical physics → ACNP
ISSN journal
00224715
Volume
72
Issue
5-6
Year of publication
1993
Pages
1391 - 1399
Database
ISI
SICI code
0022-4715(1993)72:5-6<1391:TLTOTM>2.0.ZU;2-C
Abstract
The Laplace transform is obtained for the pair distribution function b etween a pair of ions, an ion and a macroion, and a pair of macroions in an ion-dipole fluid. This fluid is a simplified model of an electro lyte with a discrete model of solvent (hard spheres with embedded poin t dipoles). From these results, an expression for the solvation force between macroions is obtained. This result consists of the classical D LVO result plus a series of corrections.