T. Petrosky et I. Prigogine, POINCARE RESONANCES AND THE LIMITS OF TRAJECTORY DYNAMICS, Proceedings of the National Academy of Sciences of the United Statesof America, 90(20), 1993, pp. 9393-9397
In previous papers we have shown that the elimination of the resonance
divergences in large Poincare systems leads to complex irreducible sp
ectral representations for the Liouville-von Neumann operator. Complex
means that time symmetry is broken and irreducibility means that this
representation is implementable only by statistical ensembles and not
by trajectories. We consider in this paper classical potential scatte
ring. Our theory applies to persistent scattering. Numerical simulatio
ns show quantitative agreement with our predictions.