MOLECULAR-MASS DISTRIBUTION OF CYCLES IN IRREVERSIBLE LINEAR POLYCONDENSATION

Authors
IRZHAK TF PEREGUDOV NI IRZHAK VI ROZENBERG BA
Citation
Tf. Irzhak et al., MOLECULAR-MASS DISTRIBUTION OF CYCLES IN IRREVERSIBLE LINEAR POLYCONDENSATION, Vysokomolekularnye soedinenia. Seria A, 35(9), 1993, pp. 20001545-20001549
Citations number
8
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
35
Issue
9
Year of publication
1993
Pages
20001545 - 20001549
Database
ISI
SICI code
0507-5475(1993)35:9<20001545:MDOCII>2.0.ZU;2-Y
Abstract
The kinetics of ring formation in the process of irreversible linear p olycondensation is studied with the numerical solution of the system o f kinetic equations. The influence of the relative rate constants on t he character of molecular mass distribution of ring products is analyz ed. In almost all cases, the molecular mass distribution is considerab ly wider than the equilibrium distribution.