REACTIVITY OF ALKOXY-BRIDGED BIS(SILYLENE)IRON COMPLEXES

Authors
UENO K TOBITA H SEKI S OGINO H
Citation
K. Ueno et al., REACTIVITY OF ALKOXY-BRIDGED BIS(SILYLENE)IRON COMPLEXES, Chemistry Letters, (10), 1993, pp. 1723-1726
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
10
Year of publication
1993
Pages
1723 - 1726
Database
ISI
SICI code
0366-7022(1993):10<1723:ROABC>2.0.ZU;2-K
Abstract
Alkoxy-bridged bis(silylene)iron complexes CpFe(CO){SiMe2...O(Me)...S iMe2} (CP = Cp, Cp'; Cp = eta-C5H5; CP' = eta-C5Me5) are unreactive t oward PhC=CPh, Et2MeSiH, and H2C=C(Me)C(Me)=CH2. With methanol, howeve r, addition occurs across the Fe=Si double bond to give, hydridobis(me thoxysilyl)iron complexes Cp(OC)FeH(SiMe2OMe)2 quantitatively.