PREDICTION OF STRUCTURAL EFFECTS OF TRIALKYLSILYL GROUPS ON REACTIVITY TOWARD NUCLEOPHILIC DISPLACEMENT AT SILICON

Authors
SHIMIZU N TAKESUE N YASUHARA S INAZU T
Citation
N. Shimizu et al., PREDICTION OF STRUCTURAL EFFECTS OF TRIALKYLSILYL GROUPS ON REACTIVITY TOWARD NUCLEOPHILIC DISPLACEMENT AT SILICON, Chemistry Letters, (10), 1993, pp. 1807-1810
Citations number
4
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
10
Year of publication
1993
Pages
1807 - 1810
Database
ISI
SICI code
0366-7022(1993):10<1807:POSEOT>2.0.ZU;2-S
Abstract
A quantitative method of predicting reactivities of trialkylsilyl grou ps relative to Me3Si toward nucleophilic displacement at silicon has b een established on the basis of statistical analyses of the rates of s olvolysis for a comprehensive series of chlorosilanes in aqueous dioxa ne.