ELECTRON-PARAMAGNETIC-RESONANCE (EPR) INVESTIGATION OF DYNAMIC-STATICJAHN-TELLER EFFECT IN CU(II) DOPED BA(5-AMINO-3,4-DIMETHYLISOXAZOLE)6(SCN)2

Authors
ISHIHARA H KRISHNAN VG
Citation
H. Ishihara et Vg. Krishnan, ELECTRON-PARAMAGNETIC-RESONANCE (EPR) INVESTIGATION OF DYNAMIC-STATICJAHN-TELLER EFFECT IN CU(II) DOPED BA(5-AMINO-3,4-DIMETHYLISOXAZOLE)6(SCN)2, Chemistry Letters, (10), 1993, pp. 1813-1816
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
10
Year of publication
1993
Pages
1813 - 1816
Database
ISI
SICI code
0366-7022(1993):10<1813:E(IOD>2.0.ZU;2-5
Abstract
Electron paramagnetic resonance(EPR) studies have been carried out on Cu(II) doped hexakis(5-amino-3,4-dimethylisoxazole)Ba(SCN)2 in the tem perature range 300 > T/K > 90. Spectra are characteristic of cupric io n substituting Ba(II) ion with Oh point symmetry at room temperature a nd subsequently distorting to a lower symmetry at 90 K. This observati on is made for the first time of Cu(II) ion substituting Ba(II) ion si tes.