PREPARATION AND STRUCTURE OF CU-II(C2H5PO3) - STRUCTURAL TRANSITION BETWEEN ITS HYDRATED AND DEHYDRATED FORMS

Authors
LEBIDEAU J BUJOLI B JOUANNEAUX A PAYEN C PALVADEAU P ROUXEL J
Citation
J. Lebideau et al., PREPARATION AND STRUCTURE OF CU-II(C2H5PO3) - STRUCTURAL TRANSITION BETWEEN ITS HYDRATED AND DEHYDRATED FORMS, Inorganic chemistry, 32(21), 1993, pp. 4617-4620
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
32
Issue
21
Year of publication
1993
Pages
4617 - 4620
Database
ISI
SICI code
0020-1669(1993)32:21<4617:PASOC->2.0.ZU;2-U
Abstract
The crystal structure of Cu(II)(C2H5PO3) has been solved ab initio usi ng direct methods and refined from X-ray powder diffraction data. This compound is monoclinic, space group P2(1)/c, with a = 10.7773(3) angs trom, b = 5.6960(2) angstrom, c = 7.6273(2) angstrom, beta = 94.47(1)- degrees, Z = 4, and V = 466.8(2) angstrom3. The Rietveld refinement ga ve R(I) = 0.047, R(p) = 0.107, R(wp) = 0.116, and R(exp) = 0.104. The layers rearrangement between its hydrated and dehydrated form is prese nted.