PHOTOCHEMISTRY OF DITHIOCARBAMATE COMPLEXES OF NI(IV) .2. MECHANISM OF PHOTOCHROMIC TRANSFORMATIONS

Authors
PLYUSNIN VF GRIVIN VP BAZHIN NM KUZNETZOVA EP LARIONOV SV
Citation
Vf. Plyusnin et al., PHOTOCHEMISTRY OF DITHIOCARBAMATE COMPLEXES OF NI(IV) .2. MECHANISM OF PHOTOCHROMIC TRANSFORMATIONS, Journal of photochemistry and photobiology. A, Chemistry, 74(2-3), 1993, pp. 129-135
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
Journal of photochemistry and photobiology. A, Chemistry → ACNP
ISSN journal
10106030
Volume
74
Issue
2-3
Year of publication
1993
Pages
129 - 135
Database
ISI
SICI code
1010-6030(1993)74:2-3<129:PODCON>2.0.ZU;2-4
Abstract
Reverse dark processes were studied to observe photochromic transforma tions in solutions of dithiocarbamate complexes of Ni(IV). The kinetic characteristics of the processes were established and the mechanism o f photochromic transformations was proposed. The molecules of the comp lex were shown to endure more than 10(4) transition cycles.