A GENERAL-APPROACH TO ARYL(CYANO)IODONIUM TRIFLATES - VERSATILE IODONIUM TRANSFER REAGENTS

Authors
ZHDANKIN VV SCHEULLER MC STANG PJ
Citation
Vv. Zhdankin et al., A GENERAL-APPROACH TO ARYL(CYANO)IODONIUM TRIFLATES - VERSATILE IODONIUM TRANSFER REAGENTS, Tetrahedron letters, 34(43), 1993, pp. 6853-6856
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
43
Year of publication
1993
Pages
6853 - 6856
Database
ISI
SICI code
0040-4039(1993)34:43<6853:AGTAT->2.0.ZU;2-T
Abstract
Aryl(cyano)iodonium triflates (ArI+CN -OTf. Ar = Ph, 4-CF3C6H4, 3,5-(C F3)2C6H3, 4-FC6H4) can be prepared in two steps from the Corresponding aryliodides by oxidation with pertrifluoroacetic acid and subsequent reaction with Me3SiOTf and Me3SiCN. These compounds react with tributy ltin derivatives of acetylenes, aromatic or heteroaromatic compounds u nder mild conditions forming the corresponding iodonium salts 5, 7, 9 in good yield.