SYNTHESIS AND CHARACTERIZATION OF TRIMETHYLPLATINUM(IV) COMPLEXES WITH (2-DIMETHYLAMINOETHYL)ORGANOCHALCOGENIDES (ME2NCH2CH2ER - E = S, SE,TE) - X-RAY CRYSTAL-STRUCTURE OF [PTME3BR(ME2NCH2CH2SC6H4ME-4)]

Authors
JAIN VK CHAUDHURY S BOHRA R
Citation
Vk. Jain et al., SYNTHESIS AND CHARACTERIZATION OF TRIMETHYLPLATINUM(IV) COMPLEXES WITH (2-DIMETHYLAMINOETHYL)ORGANOCHALCOGENIDES (ME2NCH2CH2ER - E = S, SE,TE) - X-RAY CRYSTAL-STRUCTURE OF [PTME3BR(ME2NCH2CH2SC6H4ME-4)], Polyhedron, 12(19), 1993, pp. 2377-2385
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
19
Year of publication
1993
Pages
2377 - 2385
Database
ISI
SICI code
0277-5387(1993)12:19<2377:SACOTC>2.0.ZU;2-R
Abstract
Trimethylplatinum(IV) complexes of the type [PtMe3X(Me2NCH2CH2ER)] (X = Cl, Br, I; ER = SBu(t), SC6H4Me-4, SPh, SePh, TePh) have been prepar ed and characterized by elemental analysis and NMR (H-1 arid C-13) spe ctral data. The structure of [PtMe3Br(Me2NCH2CH2SC6H4Me-4)] has been d etermined by single-crystal X-ray diffraction. The central platinum at om is coordinated by three fac-methyl groups and nitrogen, sulphur and bromine atoms. The five-membered chelate ring PtNCCS is non-planar.