CRYSTAL-STRUCTURE OF LODIETHOXYETHANOL)DILEAD(II)GREATER-THAN)-MU-IODO] OBTAINED BY DIRECT-METHODS USING LEAD(II) OXIDE AS A STARTING MATERIAL

Authors
KOKOZAY V SIENKIEWICZ A
Citation
V. Kokozay et A. Sienkiewicz, CRYSTAL-STRUCTURE OF LODIETHOXYETHANOL)DILEAD(II)GREATER-THAN)-MU-IODO] OBTAINED BY DIRECT-METHODS USING LEAD(II) OXIDE AS A STARTING MATERIAL, Polyhedron, 12(19), 1993, pp. 2421-2423
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
19
Year of publication
1993
Pages
2421 - 2423
Database
ISI
SICI code
0277-5387(1993)12:19<2421:COL>2.0.ZU;2-9
Abstract
A direct method of obtaining (Pb4I4L2)n, where L is twice deprotonated 2,2',2''-nitrilotriethanol (triethanolamine), is reported. The crysta l structure of the compound was determined by X-ray techniques. The cr ystallographically independent fragments of Pb4I4L2 are associated by bridging oxygen and iodine atoms in endless layers parallel to the bc- plane of the crystal. Tetradentate twice deprotonated triethanolamine is coordinated to lead(II) via oxygen and nitrogen atoms.