In this Letter we report the detection of the J = 4-3 transition of C3
S in the envelope of IRC + 10216. When this result is combined with pr
eviously published data at higher frequencies, it is apparent that the
re are at least two rotational temperature regimes for this molecule i
n the circumstellar envelope. We also report a tentative detection of
the J = 13-12 transition of C5S in the envelope of IRC + 10216. Assumi
ng the observed feature is due to C5S, we find that N(C5S)/N(C3S) almo
st-equal-to 0.5.