GENERALIZATION OF THE UDCA THEORY AND ITS APPLICATION TO THE ANALYSISOF THE ION-FREE LAYER THICKNESS

Authors
ANDREU R MOLERO M CALVENTE JJ CARBAJO J
Citation
R. Andreu et al., GENERALIZATION OF THE UDCA THEORY AND ITS APPLICATION TO THE ANALYSISOF THE ION-FREE LAYER THICKNESS, Journal of electroanalytical chemistry [1992], 358(1-2), 1993, pp. 49-62
Citations number
15
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
358
Issue
1-2
Year of publication
1993
Pages
49 - 62
Database
ISI
SICI code
Abstract
The modified Gouy-Chapman theory with two planes of closest approach i s generalized for any electrolyte stoichiometry, considering also the influence of the interfacial dielectric constant. Application is made to some experimental systems to derive the cation and anion distances of closest approach from the ion-free layer thickness.