Detergent efficiency of nonionic surfactant solutions with and without
electrolyte as a function of temperature has been determined. In thes
e experiments hexadecane was chosen as a model oily soil and polyester
/cotton fabrics as solid substrate. It was found that the evolution of
detergent efficiency with temperature in systems containing electroly
te followed the same trends as those of systems without electrolyte: A
s the temperature increases detergent efficiency also increases and an
optimum is reached, then a pronounced decrease is observed. However t
here is a shift in the temperature at which the optimum is obtained to
ward lower temperatures as electrolyte concentration increases. This s
hift has been attributed to the effect of salting-out electrolytes on
the HLB-temperature of ternary water/nonionic surfactant/oil systems.