S. Ban et S. Maruno, DEPOSITION OF CALCIUM-PHOSPHATE ON TITANIUM BY ELECTROCHEMICAL PROCESS IN SIMULATED BODY-FLUID, JPN J A P 2, 32(10B), 1993, pp. 120001577-120001580
Calcium phosphate coatings were produced by an electrochemical process
in a simulated body fluid. Granular precipitates were formed on the w
orking electrode after loading a cathodic potential. The products were
amorphous calcium phosphates containing magnesium, of which the compo
sition was nearly the same as calcium-deficient carbonate apatites suc
h as biological apatite. The amount of calcium and magnesium deposited
on the electrode increased in direct proportion to the square root of
loading time of cathodic potential. The diffusion process of ions aro
und the cathode was found to be a rate-determining step in the electro
chemical process of forming calcium phosphate.