We report observations of C I(P-3(1)-P-3(0)) emission at 492 GHz towar
d the starburst galaxy M82. Both the C I/C II intensity ratio and the
C/CO column density ratio are a factor of 2-5 higher than observed tow
ard Galactic photodissociation regions (PDRs) or predicted by PDR mode
ls. We argue that current PDR models are insufficient to explain the o
bservations, and propose that some of the emission is due to atomic ca
rbon existing within molecular clouds. Employing new chemical models,
which use a fast H-3+ dissociative recombination rate, we find that en
hanced cosmic-ray flux supplied by supernova remnants in the M82 starb
urst lead to an enhanced atomic carbon abundance and elevated temperat
ures deep within the molecular clouds, resulting in a higher C I emiss
ivity than found in previous PDR models.