THE EFFECTS OF FLUID DENSITY ON THE ROTATIONAL RAMAN-SPECTRUM OF HYDROGEN DISSOLVED IN SUPERCRITICAL CARBON-DIOXIDE

Authors
HOWDLE SM BAGRATASHVILI VN
Citation
Sm. Howdle et Vn. Bagratashvili, THE EFFECTS OF FLUID DENSITY ON THE ROTATIONAL RAMAN-SPECTRUM OF HYDROGEN DISSOLVED IN SUPERCRITICAL CARBON-DIOXIDE, Chemical physics letters, 214(2), 1993, pp. 215-219
Citations number
21
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
214
Issue
2
Year of publication
1993
Pages
215 - 219
Database
ISI
SICI code
0009-2614(1993)214:2<215:TEOFDO>2.0.ZU;2-X
Abstract
The rotational Raman spectrum of hydrogen dissolved in supercritical c arbon dioxide (scCO2) is investigated. As the pressure, and hence dens ity of the solution is increased, the lines broaden dramatically. The line broadening is compared with that of the vibrational line Q1(1) an d possible explanations for the behaviour, related to solvent-solute i nteractions, are discussed.