O. Sugihara et al., 2ND-HARMONIC GENERATION IN POLED POLYMER-FILMS DOPED WITH ALPHA-CYANOUNSATURATED CARBOXYLIC-ACIDS, IEICE transactions on electronics, E76C(10), 1993, pp. 1523-1528
Poled polymer films doped with novel non-linear organic materials, alp
ha-cyano unsaturated carboxylic acid (alpha-CUCA) derivatives, are pre
pared. Linear and second-order nonlinear optical properties are invest
igated. It is found that as the value of hyperpolarizability of the de
rivatives increases, the second-order nonlinear susceptibility of the
film increases. Cerenkov-type second harmonic generation (SHG) of Nd:Y
AG laser is realized in a poled polymer waveguide doped with the alpha
-CUCA material with a slight absorption at doubled wavelength.