EFFECT OF THE POLY(OXYETHYLENE) CHAIN-LENGTH OF IONIC SURFACTANTS ON THE EXTRACTION OF ALKALI-METAL IONS

Authors
SAKAI Y NABEKI K UEHARA E HIRAISHI M TAKAGI M
Citation
Y. Sakai et al., EFFECT OF THE POLY(OXYETHYLENE) CHAIN-LENGTH OF IONIC SURFACTANTS ON THE EXTRACTION OF ALKALI-METAL IONS, Bulletin of the Chemical Society of Japan, 66(10), 1993, pp. 3107-3109
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
66
Issue
10
Year of publication
1993
Pages
3107 - 3109
Database
ISI
SICI code
0009-2673(1993)66:10<3107:EOTPCO>2.0.ZU;2-8
Abstract
The following three extractants were synthesized: C12H25-O(-CH2CH2O-)n CH2-C6H3(OH)(NO2) (n = 3, 6, 9). The extraction constants for alkali m etal ions were also determined. The extractability with an extractant having three oxyethylene units decreases in the order Li+ > K+ > Na+ > Cs+ greater than or similar to Rb+; for other extractants, K+ > Rb+ > Cs+ > Na+ > Li+.