Friction and wear tests were conducted at room temperature on diamond
films deposited on silicon substrates by a microwave plasma-assisted c
hemical vapor deposition technique. Three different diamond film morph
ologies (i.e. faceted, cauliflowered and smooth) were evaluated in sli
ding contact with steel, alpha-alumina, silicon nitride and magnesia-s
tabilized zirconia balls. In addition to the uncoated balls, a few tes
ts were also conducted with silicon nitride balls coated with either a
cauliflower-type or a smooth diamond film. All the material combinati
ons, except for diamond films sliding against diamond films, exhibited
friction coefficients in the range 0.38-0.90. The average friction co
efficient for diamond films sliding against diamond films was 0.10. Th
e faceted films exhibited higher friction coefficients and higher wear
rates of the counterface materials than those for the smooth films. E
xamination of the worn surfaces of the diamond films and steel counter
faces revealed that the diamond films wore primarily by fracturing the
tips of crystals. A secondary wear mechanism of delamination within t
he diamond films was also observed. The wear of the steel counterface
occurred by abrasion.