ELECTROOXIDATION OF 2,4,6-TRIS(DIALKYLAMINO)-1,3,5-TRIAZINES - ANODICMETHOXYLATION OF THE DIMETHYLAMINO DERIVATIVE

Authors
CARIOU M ELHOBBI K SIMONET J
Citation
M. Cariou et al., ELECTROOXIDATION OF 2,4,6-TRIS(DIALKYLAMINO)-1,3,5-TRIAZINES - ANODICMETHOXYLATION OF THE DIMETHYLAMINO DERIVATIVE, Electrochimica acta, 38(17), 1993, pp. 2481-2484
Citations number
20
Categorie Soggetti
Electrochemistry
Journal title
Electrochimica acta → ACNP
ISSN journal
00134686
Volume
38
Issue
17
Year of publication
1993
Pages
2481 - 2484
Database
ISI
SICI code
0013-4686(1993)38:17<2481:EO2-A>2.0.ZU;2-Q
Abstract
The anodic oxidation of several 2,4,6-tris(dialkylamino)-1,3,5-triazin es was studied in cyclic voltammetry. The dimethylamino derivative, '' hexamethylmelamine'', a compound with an antitumoral activity, was sub jected to macroscale electrolyses; the use of a graphite plate anode p ermitted a great passivation to be overcome. In acetonitrile a demethy lation took place, whereas in methanol the successive methoxylation of the dimethylamino groups occurred.