W. Holzer et G. Seiringer, N-1 SUBSTITUTED ETHYL 4-PYRAZOLECARBOXYLATES - SYNTHESIS AND SPECTROSCOPIC INVESTIGATIONS, Journal of heterocyclic chemistry, 30(4), 1993, pp. 865-872
The synthesis of various N-1 substituted ethyl 4-pyrazolecarboxylates
via reaction of ethyl 2-formyl-3-oxo-propionate (= ethoxycarbonylmalon
dialdehyde) with appropriately substituted hydrazines is described. Mo
reover, detailed nmr-spectroscopic investigations with the title compo
unds are presented.