WAVE-PACKET DYNAMICS OF THE HGI2 PHOTODISSOCIATION REACTION IN SOLUTION

Authors
PUGLIANO N PALIT DK SZARKA AZ HOCHSTRASSER RM
Citation
N. Pugliano et al., WAVE-PACKET DYNAMICS OF THE HGI2 PHOTODISSOCIATION REACTION IN SOLUTION, The Journal of chemical physics, 99(9), 1993, pp. 7273-7276
Citations number
28
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
99
Issue
9
Year of publication
1993
Pages
7273 - 7276
Database
ISI
SICI code
0021-9606(1993)99:9<7273:WDOTHP>2.0.ZU;2-T
Abstract
Using femtosecond absorption spectroscopy, the photodissociation dynam ics of HgI2 in solution were investigated. Upon photolysis, the HgI fr agment is formed in a coherent superposition of its vibrational states . Solvent dependence of the wave packet motion is evidenced by the dif ferent results for ethanol and DMSO and between solution and gas phase .