SYNTHESIS AND MOLECULAR-STRUCTURE OF IMIDO)TRIS(MESITYL)(TRIMETHYLSILOXY)MOLYBDENUM(VI)

Authors
LAI R PIASCO V BELIN C ROS C FENEAUDUPONT J DECLERCQ JP
Citation
R. Lai et al., SYNTHESIS AND MOLECULAR-STRUCTURE OF IMIDO)TRIS(MESITYL)(TRIMETHYLSILOXY)MOLYBDENUM(VI), Polyhedron, 12(20), 1993, pp. 2513-2517
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
20
Year of publication
1993
Pages
2513 - 2517
Database
ISI
SICI code
0277-5387(1993)12:20<2513:SAMOI>2.0.ZU;2-3
Abstract
The reaction of Mo(O)(NBu(t))(OSiMe3)Cl or Mo(O)(NBu(t))(OSiMe3)2 with mesMgBr affords the imido complex [Mo(NBu(t))(mes)3(OSiMe3)] (2); the crystal structure of 2 indicates that the imido and the siloxy ligand s are linear, the Mo-N bond of 1.786(10) angstrom being one of the lon gest reported to date for a linear molybdenum imido group.