SYNTHESIS OF HETEROLEPTIC BIS(AMIDES) - CRYSTAL-STRUCTURE OF THE REPRESENTATIVE COMPOUND, [(MG[N(PH)2][N(PH)(2-PYR)])2]

Authors
HENDERSON KW MULVEY RE CLEGG W ONEIL PA
Citation
Kw. Henderson et al., SYNTHESIS OF HETEROLEPTIC BIS(AMIDES) - CRYSTAL-STRUCTURE OF THE REPRESENTATIVE COMPOUND, [(MG[N(PH)2][N(PH)(2-PYR)])2], Polyhedron, 12(20), 1993, pp. 2535-2538
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
20
Year of publication
1993
Pages
2535 - 2538
Database
ISI
SICI code
0277-5387(1993)12:20<2535:SOHB-C>2.0.ZU;2-D
Abstract
Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amin e substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically character ized and shown to be a dimer with a central, rectangular azamagnesacyc lic ring.