The solid solution compound films of (1-x)PZN-xBZN system were synthes
ized by rapid quenching using a twin-roller system. These films have a
thickness range 30-200 mum. The average grain size of thick films is
20-30 mum and the density is almost full. The phase of as-quenched thi
ck films was slightly different from that in the crystalline powders b
efore melting, but it was recovered after heat treatment. The chemical
compositions were the same after quenching. The dielectric constant o
f the composition of 0.88PZN-0.12BZN thick films was 8000 at room temp
erature at 1 kHz. This result suggests a possibility of application of
thick films made by rapid quenching to industrial use as high-permitt
ivity multilayer capacitors.