BaTiO3 particle-size dependence of ferroelectricity in BaTiO3/polymer
composites was investigated from the viewpoints of the crystal phase i
n BaTiO3 powder and piezoelectric properties in BaTiO3/polymer composi
tes. The crystal phase of BaTiO3 powder was transformed from tetragona
l to pseudocubic at a critical particle size of 0.1 to 0.2 mum at room
temperature. The piezoelectric charge constant (d33) and hydrostatic
piezoelectric constant (d(h)) were obtained through poling treatment,
although their values were small in BaTiO3/polymer composite using the
pseudocubic BaTiO3 powder.