REACTION OF NO WITH CP-ASTERISK-3CO3(MU-H)4 PRESERVES THE TRICOBALT CLUSTER AND PRODUCES CP-ASTERISK-3CO3(MU-3-NO)2

Authors
CASEY CP WIDENHOEFER RA HAYASHI RK
Citation
Cp. Casey et al., REACTION OF NO WITH CP-ASTERISK-3CO3(MU-H)4 PRESERVES THE TRICOBALT CLUSTER AND PRODUCES CP-ASTERISK-3CO3(MU-3-NO)2, Inorganica Chimica Acta, 212(1-2), 1993, pp. 81-85
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
212
Issue
1-2
Year of publication
1993
Pages
81 - 85
Database
ISI
SICI code
0020-1693(1993)212:1-2<81:RONWCP>2.0.ZU;2-U
Abstract
CP3Co3(mu-H)4 (4) reacts with NO to produce CP*3Co3(mu3-NO)2 (3) whic h was characterized by X-ray crystallography. 3 is a diamagnetic 48 el ectron tricobalt cluster in which an equilateral triangular array of c obalt atoms (Co-Co(av) = 2.423(2) angstrom) is capped on each face by a mu3-NO ligand (Co-mu3-NO(av) = 1.863(7) angstrom).