GAS-PHASE GENERATION AND CHARACTERIZATION OF HYDROGEN-CYANIDE N-METHYLIDE

Authors
GOLDBERG N IRAQI M SCHWARZ H
Citation
N. Goldberg et al., GAS-PHASE GENERATION AND CHARACTERIZATION OF HYDROGEN-CYANIDE N-METHYLIDE, Chemische Berichte, 126(10), 1993, pp. 2353-2355
Citations number
43
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
126
Issue
10
Year of publication
1993
Pages
2353 - 2355
Database
ISI
SICI code
0009-2940(1993)126:10<2353:GGACOH>2.0.ZU;2-E
Abstract
The recently described (Maier et al. [2]) title compound is not only v iable in an argon matrix (10 K) but is also accessible in the gas phas e. Electron impact ionization of (CH3)3CCX2NC (X = H, D) gives rise to HCNCX2+., which can be successfully neutralized in a beam experiment.