J. Albert et al., MASKLESS WRITING OF SUBMICROMETER GRATINGS IN FUSED-SILICA BY FOCUSEDION-BEAM IMPLANTATION AND DIFFERENTIAL WET ETCHING, Applied physics letters, 63(17), 1993, pp. 2309-2311
Surface relief gratings with submicrometer periods have been fabricate
d in silica by ion implantation with a focused ion beam, followed by e
tching in diluted hydrofluoric acid. Implanted silica etches three tim
es faster than unimplanted silica and groove depths of the order of 30
0 nm have been achieved. The method does not require photolithography
or masking layers, allows arbitrary patterns to be defined, and may be
used to fabricate diffractive optical elements or grating filters in
optical waveguides.