Spline fitting has been used in processing measurements on the pressur
e dependence of the burning rate to obtain additional information on t
he variation in the pressure coefficient nu as affected by grain size
and composition, as well as by the nature of the components. Conclusio
ns are drawn on the burning mechanism. The peak on nu(p) is due to ser
ial-parallel conversion of APC in the condensed and gas phases and to
changes in the relative significance of the chemical stages. There is
a minimum at elevated pressures for many propellants, which in some ca
ses is transformed into a plateau or inflection on account of interact
ion between the fuel and the oxidizing agent in the diffusion-kinetic
hydrocarbon flame.