HYDROFORMYLATION OF ALLYL ALCOHOL IN THE PRESENCE OF MODIFIED RHODIUMCATALYSTS

Authors
KORNEYEVA GA CHEKHOVA RV POTARIN MM KURKIN VI SLIVINSKII YV LOKTEV SM
Citation
Ga. Korneyeva et al., HYDROFORMYLATION OF ALLYL ALCOHOL IN THE PRESENCE OF MODIFIED RHODIUMCATALYSTS, Petroleum chemistry, 33(3), 1993, pp. 236-246
Citations number
18
Categorie Soggetti
Energy & Fuels","Engineering, Chemical
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
33
Issue
3
Year of publication
1993
Pages
236 - 246
Database
ISI
SICI code
0965-5441(1993)33:3<236:HOAAIT>2.0.ZU;2-6
Abstract
Reactions of hydroformylation of allyl alcohol and propene differ cons iderably. Thus certain peculiar features have been observed in the kin etic mechanisms of hydroformylation of propene and allyl alcohol in th e presence of HRh(CO)(PPh)(3) [1, 2]; these include intense oxidation of the PPh(3) contained in the rhodium catalyst under the action of th e OH group of allyl alcohol [3], and also differences in regioselectiv ity when these substrates are used.