OXIDATION BY OXYGEN OVER HETEROGENEOUS CATALYSTS

Authors
ZAKHAROV AN BURENKOVA LN VOBLIKOVA VA
Citation
An. Zakharov et al., OXIDATION BY OXYGEN OVER HETEROGENEOUS CATALYSTS, Journal of applied chemistry of the USSR, 65(10), 1992, pp. 1818-1823
Citations number
8
Categorie Soggetti
Chemistry Applied
Journal title
Journal of applied chemistry of the USSR → ACNP
ISSN journal
0021888X
Volume
65
Issue
10
Year of publication
1992
Part
1
Pages
1818 - 1823
Database
ISI
SICI code
0021-888X(1992)65:10<1818:OBOOHC>2.0.ZU;2-7
Abstract
A pulse microcatalytic method has been used to study the oxidation of CO by atmospheric oxygen over the heterogeneous catalysts APK-2, Pd,Ce /Al2O3, La,Ni/Al2O3, Tseokar-2 zeolite, and PcFe/NaY [PcFe is an Fe(II ) phthalocyanine complex]. The effective activation parameters E(a) an d k0 have been calculated for the reaction. For the systems listed abo ve, the respective values are 17, 45, 57, 25, and 32 kJ/mole, and 0.18 8, 815.6, 71.95, 1.589, and 1.14 moles-MPa-1.sec-1.g-1. The catalytic properties of these systems have been compared.