GAS-GENERATING POROUS-ELECTRODES WITH SOLID POLYMERIC ELECTROLYTES - SURFACE DEPOSITION OF CATALYSTS

Authors
Citation
Yg. Chirkov, GAS-GENERATING POROUS-ELECTRODES WITH SOLID POLYMERIC ELECTROLYTES - SURFACE DEPOSITION OF CATALYSTS, Russian journal of electrochemistry, 33(1), 1997, pp. 47-54
Citations number
34
Categorie Soggetti
Electrochemistry
ISSN journal
10231935
Volume
33
Issue
1
Year of publication
1997
Pages
47 - 54
Database
ISI
SICI code
1023-1935(1997)33:1<47:GPWSPE>2.0.ZU;2-L
Abstract
Electron-microscopic studies show that, in two-component gas-generatin g porous electrodes with a solid polymeric electrolyte (SPE), the aver age size of SPE grains is much greater than the average size of platin um-black grains (PEG). The PEG can both fill the space between the SPE grains and cover their surface. The calculations in this work show th at the preferential surface deposition of PEG makes it possible to sub stantially reduce (by two and even three orders of magnitude) the nece ssary amount of expensive catalysts-platinum-group metals.