THERMODYNAMIC AND CONDUCTOMETRIC STUDIES ON NAI SOLUTIONS IN WATER-ISOBUTANOL MIXTURES AT 298.15-K

Citation
A. Bald et al., THERMODYNAMIC AND CONDUCTOMETRIC STUDIES ON NAI SOLUTIONS IN WATER-ISOBUTANOL MIXTURES AT 298.15-K, Physics and chemistry of liquids, 26(2), 1993, pp. 121-133
Citations number
38
Categorie Soggetti
Chemistry Physical","Physics, Condensed Matter
ISSN journal
00319104
Volume
26
Issue
2
Year of publication
1993
Pages
121 - 133
Database
ISI
SICI code
0031-9104(1993)26:2<121:TACSON>2.0.ZU;2-7
Abstract
The electric conductivity of NaI solutions in water-isobutanol mixture s in the complete miscibility range of the alcohol has been measured a nd analysed using the Fuoss-Justice equation. The electromotive force of the cell: glass electrode (Na)\NaI\AgI, Ag in the same binary mixtu res has been determined. The standard enthalpies of solution of NaI ha ve been recalculated and the thermodynamic functions DELTAG(t)-degrees and DELTAS(t)-degrees have also been calculated taking into account i on association.