U. Tegtmeyer et al., GAS-ANALYSIS BY IMR-MS - A COMPARISON TO CONVENTIONAL MASS-SPECTROMETRY, Fresenius' journal of analytical chemistry, 347(6-7), 1993, pp. 263-268
Ionisation of small molecules via ion-molecule reactions (IMR) offers
the possibility to reduce fragmentation caused by high energy electron
impact ionisation. Widely varying rate constants for the IMR processe
s allow to introduce additional species selectivity together with the
mass selection in a quadrupole system. A comparison between low energy
electron impact ionisation and IMR illustrates the potential of this
new ionisation method in gas analysis applications.