GAS-ANALYSIS BY IMR-MS - A COMPARISON TO CONVENTIONAL MASS-SPECTROMETRY

Citation
U. Tegtmeyer et al., GAS-ANALYSIS BY IMR-MS - A COMPARISON TO CONVENTIONAL MASS-SPECTROMETRY, Fresenius' journal of analytical chemistry, 347(6-7), 1993, pp. 263-268
Citations number
12
Categorie Soggetti
Chemistry Analytical
ISSN journal
09370633
Volume
347
Issue
6-7
Year of publication
1993
Pages
263 - 268
Database
ISI
SICI code
0937-0633(1993)347:6-7<263:GBI-AC>2.0.ZU;2-R
Abstract
Ionisation of small molecules via ion-molecule reactions (IMR) offers the possibility to reduce fragmentation caused by high energy electron impact ionisation. Widely varying rate constants for the IMR processe s allow to introduce additional species selectivity together with the mass selection in a quadrupole system. A comparison between low energy electron impact ionisation and IMR illustrates the potential of this new ionisation method in gas analysis applications.