ONE-STEP SYNTHESIS OF HETEROPOLYCYCLES, INDOLIZINOQUINOLIZINES BY THEREACTION OF EITHER PYRIDYLKETENE DITHIOACETAL WITH PYRIDINIUM SALT ORPYRIDINIUMKETENE DITHIOACETAL WITH PYRIDYLACETONITRILE
Y. Matsuda et al., ONE-STEP SYNTHESIS OF HETEROPOLYCYCLES, INDOLIZINOQUINOLIZINES BY THEREACTION OF EITHER PYRIDYLKETENE DITHIOACETAL WITH PYRIDINIUM SALT ORPYRIDINIUMKETENE DITHIOACETAL WITH PYRIDYLACETONITRILE, Tetrahedron, 49(44), 1993, pp. 9947-9954
The heteropolycycles, indolizinoquinolizines (7, 8, 20) were obtained
by the reaction of either pyridylketene dithioacetal (2) with two mola
r equivalents of pyridinium salts (4a-c) or pyridiniumketene dithioace
tal (19) with two molar equivalents of pyridylacetonitrile (3) in the
presence of triethylamine.