EFFICIENT STEREOCONTROLLED GLYCOSIDATION OF SECONDARY SUGAR HYDROXYLSBY SILICON TETHERED INTRAMOLECULAR GLYCOSIDATION

Authors
Citation
M. Bols, EFFICIENT STEREOCONTROLLED GLYCOSIDATION OF SECONDARY SUGAR HYDROXYLSBY SILICON TETHERED INTRAMOLECULAR GLYCOSIDATION, Tetrahedron, 49(44), 1993, pp. 10049-10060
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
49
Issue
44
Year of publication
1993
Pages
10049 - 10060
Database
ISI
SICI code
0040-4020(1993)49:44<10049:ESGOSS>2.0.ZU;2-8
Abstract
Dissaccharides containing 1.2-cis glycoside linkages were synthesized by an efficient stereocontrolled two step process involving a silicon tethering step, to a dimethylsilyl acetal followed by intramolecular g lycosidation with N-iodosuccinimide in nitromethane.