SI-C-BOND CLEAVAGE IN 1-ORGANYLSILATRANES BY BROMINE OR IODINE CHLORIDE

Authors
VORONKOV MG BARYSHOK VP LAZAREVA NF
Citation
Mg. Voronkov et al., SI-C-BOND CLEAVAGE IN 1-ORGANYLSILATRANES BY BROMINE OR IODINE CHLORIDE, Russian chemical bulletin, 45(8), 1996, pp. 1970-1972
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
8
Year of publication
1996
Pages
1970 - 1972
Database
ISI
SICI code
1066-5285(1996)45:8<1970:SCI1BB>2.0.ZU;2-B
Abstract
The Si-C bond in 1-organylsilatranes is cleaved by bromine or iodine c hloride to yield 1-bromo- or 1-chlorosilatrane respectively. In the pr esence of Et(2)O or THF and under the action of dioxane dibromide, 1-h alosilatranes are formed together with 1-alkoxy- and 1-(omega-haloalko xy)silatranes.